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If I was isekai'd into the PMD world, my actions would depend heavily on how much of my memory I kept. It seems most of you guild members kept at least most of yours, so surely I'd retain enough memories to remember my irl job. As a scrub tech, I could provide the town with modern knowledge on infection control and aseptic technique. I'm sure having a medical professional around would be handy for an emerging guild full of Pokemon who are entirely new to their bodies.
Having said that, I'd probably lurk around for a while before introducing myself and setting up shop. When in doubt, lurk moar. That's my motto.