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Sticky web is the name of the game, it's the only mon besides smeargle that gets webs + rocks, and unlike smeargle has the bulk to set them up multiple times a game if required. Typically you want a mental herb because it's still total tauntbait, but I rarely see taunt on wifi, so you could probably get away with gluttony and one of the 50% berries like wiki. Watch out for magic bounce. If they have a magic bounce mon or mon that commonly runs taunt, use your brain and lead with something else. Pairs well with sweepers who are just a touch below average in the speed department (mega tyranitar, for example), ghost types to discourage rapid spin, and either a defiant mon like bisharp or primeape and/or a contrary mon like serperior to discourage defog.
Go nuts.