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as for gardevoirs being turned into wives. i feel its plausible if one of these conditions are met:
>they have a weak will and can't fend off those desires so come to accept the relationship as their life, i.e. grooming
>they see it as part of trainer/pokemon bonding as a method of getting stronger, or in gardevoir's case, a logical extension of the typical gardevoir MO
>there is a mental struggle between the two and the pokemon breaks first and she accepts her place as his slave because he dominated her and she can respect that. doesn't mean she's broken. she just accepts it for now
>the pokemon is actually just attracted to humans (just as deviant as a human wanting a pokewife)
>social pressures, i.e. if there are other human/pokemon couples the pokemon may feel compelled to act in that manner
i doubt things like hypnosis would work because its just temporary. unless you get one of those cool glowy visors and make her wear it all the time