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Misty and May's boobs are equal size except for one shot where May's appear to be visible despite her being turned all the way around. There are shots of Misty with her chest distended just as much as May's
With May it's more noticable specifically because her shirt conforms to her chest while Misty's just goes straight down
Most female characters have their shirts drawn like Misty, creating the visual illusion that May has an unusually large chest
This has been a PSA