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celadon has always had a strangely comfortable atmosphere to me.
azalea being a small forest town where they burn charcoal and have slowpoke chilling everywhere is great
lavaridge being nestled near a volcano, but having hot springs and a thriving culture has always felt neat
canalave is a port town, which is about as comfy as sinnoh gets desu
village bridge is the comfiest place in pokemon history, bar none
laverre's autumn aesthetic kind of speaks for itself
exeggutor island has that cute moment with lillie in the original sm games and i look back on that pretty fondly
circhester being both the token snow city but also a hot springs city alongside the shops and restaurants you'd expect in galar make it pretty intriguing
cortondo is a cute little town, with fun architecture and its fixation on olives reminds me of some of the small towns near where i live
agate just screams 'lush natural oasis' being a big, green place where trees grow in the desert that is orre. i think the harmonica music and mostly-elderly population helps
vientown quite literally being your base of operations in almia made it easy to look forward to returning after all the dangerous missions in that game
aqua resort is a gorgeous city in a region where settlements are very few and far between.
any regions i didn't mention i don't know well enough, but that's my two cents