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Suisei is nothing if not opportunistic. She always tries to push herself forward. And Mori is the biggest Holo musician right now, like it or not. So of course Suisei noticed her. Does she actually like Mori? Sure, why not, Mori is not a bad person, just a stunningly dumb one. But this is a partnership first and foremost, Suisei wouldn't be doing this if Mori had nothing of value to offer, they would just be friendly Holos, maybe doing occasional collab streams. And that doesn't make Suisei a bad person either, she's just married to her idol career, so she puts that long before her personal life.